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Article
Zirconium Diboride with High Thermal Conductivity
Journal of the American Ceramic Society
  • Jason M. Lonergan
  • William Fahrenholtz, Missouri University of Science and Technology
  • Greg Hilmas, Missouri University of Science and Technology
Abstract

Thermal properties were characterized for zirconium diboride produced by reactive hot pressing and compared to ZrB2 ceramics that were hot pressed from commercial powders. No sintering additives were used in either process. Thermal conductivity was calculated from measured values of heat capacity, thermal diffusivity, and density for temperatures ranging from 298 to 2273 K. ZrB2 produced by reactive hot pressing achieved near full density, but had a small volume fraction of ZrO2, whereas hot-pressed ZrB2 contained porosity and carbon inclusions. Reactive hot pressing produced a ceramic with higher thermal diffusivity and heat capacity, resulting in thermal conductivities of 127 W·(m·K)-1 at 298 K and 80 W·(m·K)-1 at 2273 K, which were up to ~30% higher than typically reported for hot-pressed ZrB2.

Department(s)
Materials Science and Engineering
Keywords and Phrases
  • Ceramic materials,
  • Hot pressing,
  • Sintering,
  • Specific heat,
  • Zirconium compounds,
  • A-ceramics,
  • Commercial powders,
  • High thermal conductivity,
  • Measured values,
  • Reactive hot pressing,
  • Sintering additives,
  • Zirconium diboride,
  • Thermal conductivity
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2014 Blackwell Publishing Inc., All rights reserved.
Publication Date
6-1-2014
Publication Date
01 Jun 2014
Citation Information
Jason M. Lonergan, William Fahrenholtz and Greg Hilmas. "Zirconium Diboride with High Thermal Conductivity" Journal of the American Ceramic Society Vol. 97 Iss. 6 (2014) p. 1689 - 1691 ISSN: 0002-7820; 1551-2916
Available at: http://works.bepress.com/greg-hilmas/7/