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Article
A Super-Hard High Entropy Boride Containing Hf, Mo, Ti, V, and W
Journal of the American Ceramic Society
  • Suzana Filipovic
  • Nina Obradovic
  • Greg E. Hilmas, Missouri University of Science and Technology
  • William G. Fahrenholtz, Missouri University of Science and Technology
  • Donald W. Brenner
  • Jon Paul Maria
  • Douglas E. Wolfe
  • Eva Zurek
  • Xiomara Campilongo
  • Stefano Curtarolo
Abstract

Super-Hard (Hf,Mo,Ti,V,W)B2 Was Synthesized by Boro-Carbothermal Reduction and Densified by Spark Plasma Sintering. This Composition Was Produced for the First Time as a Single-Phase Ceramic in the Present Research. the Optimized Ceramic Had a Single Hexagonal AlB2-Type Crystalline Phase with a Grain Size of 3.8 µm and Homogeneous Distribution of the Constituent Metals. the Vickers Hardness Exhibited the Indentation Size Effect, Increasing from 27 GPa at a Load of 9.8 N to as High as 66 GPa at a Load of 0.49 N. This is the Highest Hardness Reported to Date for High Entropy Boride Ceramics.

Department(s)
Materials Science and Engineering
Publication Status
Full Access
Comments

Office of Naval Research, Grant N00014‐21‐1‐2515

Keywords and Phrases
  • borides,
  • hardness,
  • scanning electron microscopy,
  • spark plasma sintering
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2024 Wiley, All rights reserved.
Publication Date
1-1-2024
Publication Date
01 Jan 2024
Disciplines
Citation Information
Suzana Filipovic, Nina Obradovic, Greg E. Hilmas, William G. Fahrenholtz, et al.. "A Super-Hard High Entropy Boride Containing Hf, Mo, Ti, V, and W" Journal of the American Ceramic Society (2024) ISSN: 1551-2916; 0002-7820
Available at: http://works.bepress.com/greg-hilmas/326/