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Article
Processing and Mechanical Properties of Hot-Pressed Zirconium Diboride – Zirconium Carbide Ceramics
Journal of the European Ceramic Society
  • Eric W. Neuman
  • William Fahrenholtz, Missouri University of Science and Technology
  • Gregory E. Hilmas, Missouri University of Science and Technology
Abstract

ZrB2 was mixed with 0.5 wt% carbon and up to 10 vol% ZrC and densified by hot-pressing at 2000 °C. All compositions were > 99.8% dense following hot-pressing. The dense ceramics contained 1–1.5 vol% less ZrC than the nominal ZrC addition and had between 0.5 and 1 vol% residual carbon. Grain sizes for the ZrB2 phase decreased from 10.1 µm for 2.5 vol% ZrC to 4.2 µm for 10 vol% ZrC, while the ZrC cluster size increased from 1.3 µm to 2.2 µm over the same composition range. Elastic modulus was ~505 GPa and toughness was ~2.6 MPa·m½ for all compositions. Vickers hardness increased from 14.1 to 15.3 GPa as ZrC increased from 2.5 to 10 vol%. Flexure strength increased from 395 MPa for 2.5 vol% ZrC to 615 MPa for 10 vol% ZrC. Griffith-type analysis suggests ZrB2 grain pullout from machining as the strength limiting flaw for all compositions.

Department(s)
Materials Science and Engineering
Comments

Air Force Office of Scientific Research, Grant FA9550-09-1-0168

Keywords and Phrases
  • Hot-pressing,
  • Mechanical properties,
  • Zirconium carbide,
  • Zirconium diboride
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2023 Elsevier, All rights reserved.
Publication Date
9-1-2022
Publication Date
01 Sep 2022
Citation Information
Eric W. Neuman, William Fahrenholtz and Gregory E. Hilmas. "Processing and Mechanical Properties of Hot-Pressed Zirconium Diboride – Zirconium Carbide Ceramics" Journal of the European Ceramic Society Vol. 42 Iss. 11 (2022) p. 4472 - 4478 ISSN: 1873-619X; 0955-2219
Available at: http://works.bepress.com/greg-hilmas/304/