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Article
Low-Temperature Sintering of Single-Phase, High-Entropy Carbide Ceramics
Journal of the American Ceramic Society
  • Lun Feng
  • William Fahrenholtz, Missouri University of Science and Technology
  • Greg Hilmas, Missouri University of Science and Technology
Abstract

Dense (Hf, Zr, Ti, Ta, Nb)C high-entropy ceramics were produced by hot pressing (HP) of carbide powders synthesized by carbothermal reduction (CTR). The relative density increased from 95% to 99.3% as the HP temperature increased from 1750°C to 1900°C. Nominally phase pure ceramics with the rock salt structure had grain sizes ranging from 0.6 µm to 1.2 µm. The mixed carbide powders were synthesized by high-energy ball milling (HEBM) followed by CTR at 1600°C, which resulted in an average particle size of ~100 nm and an oxygen content of 0.8 wt%. Low sintering temperature, high relative densities, and fine grain sizes were achieved through the use of synthesized powders. These are the first reported results for low-temperature densification and fine microstructure of high-entropy carbide ceramics.

Department(s)
Materials Science and Engineering
Comments
This research was conducted as part of the Enabling Materials for Extreme Environments Signature Area at Missouri S&T. The use of the Advanced Materials Characterization Laboratory is also acknowledged.
Keywords and Phrases
  • Densification,
  • High-Entropy Carbide Ceramics,
  • Mechanical Properties,
  • Microstructure
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2019 The American Ceramic Society, All rights reserved.
Publication Date
12-1-2019
Publication Date
01 Dec 2019
Disciplines
Citation Information
Lun Feng, William Fahrenholtz and Greg Hilmas. "Low-Temperature Sintering of Single-Phase, High-Entropy Carbide Ceramics" Journal of the American Ceramic Society Vol. 102 Iss. 12 (2019) p. 7217 - 7224 ISSN: 0002-7820; 1551-2916
Available at: http://works.bepress.com/greg-hilmas/240/