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Article
Thermal Properties of (Zr,TM)B₂ Solid Solutions with TM = Hf, Nb, W, Ti, and Y
Journal of the American Ceramic Society
  • Devon L. McClane
  • William Fahrenholtz, Missouri University of Science and Technology
  • Greg Hilmas, Missouri University of Science and Technology
Abstract

The thermal properties were investigated for hot-pressed zirconium diboride - transition-metal boride solid solutions. The transition-metal additives included hafnium, niobium, tungsten, titanium, and yttrium. The nominal additions were equivalent to 3 at.% of each metal with respect to zirconium. Powders were hot-pressed to nearly full density at 2150⁰C using 0.5 wt% carbon as a sintering aid. Thermal diffusivity was measured using the laser flash method. Thermal conductivity was calculated from the thermal diffusivity results using temperature-dependent values for density and heat capacity. At 25⁰C, the thermal conductivity ranged from 88 to 34 W·(m·K)-1 for specimens with various additives. Electrical resistivity measurements and the Wiedemann-Franz law were used to calculate the electron contribution of the thermal conductivity and revealed that thermal conductivity was dominated by the electron contribution. The decrease in thermal conductivity correlated with a decrease in unit cell volume, indicating that lattice strain may affect both phonon and electron transport in ZrB2.

Department(s)
Materials Science and Engineering
Keywords and Phrases
  • Hafnium,
  • Sintering,
  • Solid solutions,
  • Thermodynamic properties,
  • Zirconium,
  • Electrical resistivity measurements,
  • Electron transport,
  • Laser flash methods,
  • Lattice strain,
  • Temperature dependent,
  • Unit-cell volume,
  • Wiedemann-Franz law,
  • Zirconium diboride,
  • Thermal conductivity
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2014 Blackwell Publishing Inc., All rights reserved.
Publication Date
5-1-2014
Publication Date
01 May 2014
Citation Information
Devon L. McClane, William Fahrenholtz and Greg Hilmas. "Thermal Properties of (Zr,TM)B₂ Solid Solutions with TM = Hf, Nb, W, Ti, and Y" Journal of the American Ceramic Society Vol. 97 Iss. 5 (2014) p. 1552 - 1558 ISSN: 0002-7820; 1551-2916
Available at: http://works.bepress.com/greg-hilmas/195/