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Article
Sintering Mechanisms and Kinetics for Reaction Hot-Pressed ZrB₂
Journal of the American Ceramic Society
  • Jason M. Lonergan
  • William Fahrenholtz, Missouri University of Science and Technology
  • Greg Hilmas, Missouri University of Science and Technology
Abstract

Sintering mechanisms and kinetics were investigated for ZrB2 ceramics produced using reaction hot pressing. Specimens were sintered at temperatures ranging from 1800-C to 2100-C for times up to 120 min. ZrB2 was the primary phase, although trace amounts of ZrO2 and C were also detected. Below 2000⁰C, the densification mechanism was grain-boundary diffusion with an activation energy of 241 ± 41 kJ/mol. At higher temperatures, the densification mechanism was lattice diffusion with an activation energy of 695 ± 62 kJ/mol. Grain growth exponents were determined to be ~4.5, which indicated that a grain pinning mechanism was active in both temperature regimes. The diffusion coefficients for grain growth were 1.5 x 10-16 cm4/s at 1900⁰C and 2.1 x 10-15 cm4/s at 2100⁰C. This study revealed that dense ZrB2 ceramics can be produced by reactive hot pressing in shorter times and at lower temperatures than conventional hot pressing of commercial powders.

Department(s)
Materials Science and Engineering
Keywords and Phrases
  • Activation energy,
  • Ceramic materials,
  • Chemical activation,
  • Diffusion,
  • Grain boundaries,
  • Hot pressing,
  • Reaction kinetics,
  • Sintering,
  • Commercial powders,
  • Densification mechanisms,
  • Grain growth exponent,
  • Grain-boundary diffusion,
  • Lower temperatures,
  • Reactive hot pressing,
  • Sintering mechanism,
  • Temperature regimes
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2015 Blackwell Publishing Inc., All rights reserved.
Publication Date
8-1-2015
Publication Date
01 Aug 2015
Citation Information
Jason M. Lonergan, William Fahrenholtz and Greg Hilmas. "Sintering Mechanisms and Kinetics for Reaction Hot-Pressed ZrB₂" Journal of the American Ceramic Society Vol. 98 Iss. 8 (2015) p. 2344 - 2351 ISSN: 0002-7820; 1551-2916
Available at: http://works.bepress.com/greg-hilmas/178/