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Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding
Chemical Communications (2016)
  • Helena Isla, Institut des Sciences Chimiques de Rennes
  • Monika Srebro-Hooper, Jagiellonian University, Poland
  • Marion Jean, Aix Marseille Université
  • Nicolas Vanthuyne, Aix Marseille Université
  • Thierry Roisnel, Institut des Sciences Chimiques de Rennes
  • Jamie L. Lunkley, San Jose State University
  • Gilles Muller, San Jose State University
  • J. A. Gareth-Williams, University of Durham
  • Jochen Autschbach, SUNY University at Buffalo
  • Jeanne Crassous, Institut des Sciences Chimiques de Rennes
Abstract
The molecular conformation of a bis-helicenic terpyridine system is strongly modified upon binding to Zn(II) ion, a process that is accompanied by large changes in the optical and chiroptical properties. This system affords a new type of helicene-based chiroptical switching.
Disciplines
Publication Date
2016
DOI
10.1039/C6CC01748G
Publisher Statement
This article was originally published in Chemical Communications, 52, 35, by the Royal Society of Chemistry, 2016. It can be found online at this link.
Citation Information
Helena Isla, Monika Srebro-Hooper, Marion Jean, Nicolas Vanthuyne, et al.. "Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding" Chemical Communications Vol. 52 Iss. 35 (2016) p. 5932 - 5935
Available at: http://works.bepress.com/gilles_muller/58/
Creative Commons license
Creative Commons License
This work is licensed under a Creative Commons CC_BY-NC International License.