Skip to main content
Article
Organic synthesis using bridgehead carbocations and bridgehead enones
Chemical Reviews
  • George A. Kraus, Iowa State University
  • Yung Son Hon, Iowa State University
  • P.J. Thomas, Iowa State University
  • Steve Laramay, Iowa State University
  • Spiros Liras, Iowa State University
  • Jeff Hanson, Iowa State University
Document Type
Article
Publication Version
Published Version
Publication Date
11-1-1989
DOI
10.1021/cr00097a013
Abstract

The development of new pathways by which organic molecules can be stereoselectively constructed remains an important direction for organic chemistry. The palladium-mediated cyclizations of Trost,' Stille? Hegedus,3 Larock," Negishi: and Overman6 and the radical cyclization reactions of Keck,' Stork: Hart: Curran,Io Barton," and Beckwith12 represent important new strategies. A comparatively unstudied strategy is the formation of bicyclic or tricyclic systems via reactive bridgehead intermediates.

Comments

Reprinted (adapted) with permission from Chemical Reviews, 89(7); 1591-1598. Doi: 10.1021/cr00097a013. Copyright 1989 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
George A. Kraus, Yung Son Hon, P.J. Thomas, Steve Laramay, et al.. "Organic synthesis using bridgehead carbocations and bridgehead enones" Chemical Reviews Vol. 89 Iss. 7 (1989) p. 1591 - 1598
Available at: http://works.bepress.com/george_kraus/78/