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Article
Synthesis of isophthalates from methyl coumalate
RSC Advances
  • George A. Kraus, Iowa State University
  • Shuai Wang, Iowa State University
Document Type
Article
Publication Version
Published Version
Publication Date
12-15-2017
DOI
10.1039/C7RA12935A
Abstract

Methyl coumalate reacts with enol ethers to form stable adducts which can be converted into isophthalates in good to excellent yields. Alkyl vinyl ethers afford higher yields of isophthalates than enol silyl ethers. The adduct of the enol silyl ether of acetophenone with methyl coumalate reacted with PTSA to produce a styryl coumalate.

Comments

This article is published as Kraus, George A. and Shuai Wang. "Synthesis of isophthalates from methyl coumalate." RSC Advances 7, no. 89 (2017): 56760-56763. DOI: 10.1039/C7RA12935A. Posted with permission.

Creative Commons License
Creative Commons Attribution 3.0
Copyright Owner
The Royal Society of Chemistry
Language
en
File Format
application/pdf
Citation Information
George A. Kraus and Shuai Wang. "Synthesis of isophthalates from methyl coumalate" RSC Advances Vol. 7 Iss. 89 (2017) p. 56760 - 56763
Available at: http://works.bepress.com/george_kraus/230/