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Article
Rearrangements of bridgehead bromides. A direct synthesis of epi-modhephene
The Journal of Organic Chemistry
  • George A. Kraus, Iowa State University
  • Jianmin Shi, Iowa State University
Document Type
Article
Publication Version
Published Version
Publication Date
9-1-1990
DOI
10.1021/jo00307a001
Abstract

Summary: The reaction of nucleophiles with bridgehead bromides 3 and 4 affords rearrangement products resulting from addition of the nucleophile to the carbonyl group followed by ring contraction. This rearrangement has been employed in a direct synthesis of epi-modhephene.

Comments

Reprinted (adapted) with permission from The Journal of Organic Chemistry,55(20); 5423-5424. Doi: 10.1021/jo00307a001. Copyright 1990 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
George A. Kraus and Jianmin Shi. "Rearrangements of bridgehead bromides. A direct synthesis of epi-modhephene" The Journal of Organic Chemistry Vol. 55 Iss. 20 (1990) p. 5423 - 5424
Available at: http://works.bepress.com/george_kraus/175/