Rearrangements of bridgehead bromides. A direct synthesis of epi-modhepheneThe Journal of Organic Chemistry
Publication VersionPublished Version
AbstractSummary: The reaction of nucleophiles with bridgehead bromides 3 and 4 affords rearrangement products resulting from addition of the nucleophile to the carbonyl group followed by ring contraction. This rearrangement has been employed in a direct synthesis of epi-modhephene.
Copyright OwnerAmerican Chemical Society
Citation InformationGeorge A. Kraus and Jianmin Shi. "Rearrangements of bridgehead bromides. A direct synthesis of epi-modhephene" The Journal of Organic Chemistry Vol. 55 Iss. 20 (1990) p. 5423 - 5424
Available at: http://works.bepress.com/george_kraus/175/