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Article
Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes
The Journal of Organic Chemistry
  • George A. Kraus, Iowa State University
  • Yung Son Hon, Iowa State University
Document Type
Article
Publication Version
Published Version
Publication Date
11-1-1985
DOI
10.1021/jo00223a035
Abstract

Both intramolecular and intermolecular reactions of bridgehead carbocations are described. The carbocations are best generated from the corresponding halide with silver triflate. The carbocations reacted effectively with allyltrimethylsilane, ethyl acetoacetate, benzene, and enol silyl ethers. Bridgehead radicals were also examined.

Comments

Reprinted (adapted) with permission from The Journal of Organic Chemistry, 50(23); 4605-4608. Doi: 10.1021/jo00223a035. Copyright 1985 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
George A. Kraus and Yung Son Hon. "Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes" The Journal of Organic Chemistry Vol. 50 Iss. 23 (1985) p. 4605 - 4608
Available at: http://works.bepress.com/george_kraus/172/