Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanesThe Journal of Organic Chemistry
Publication VersionPublished Version
AbstractBoth intramolecular and intermolecular reactions of bridgehead carbocations are described. The carbocations are best generated from the corresponding halide with silver triflate. The carbocations reacted effectively with allyltrimethylsilane, ethyl acetoacetate, benzene, and enol silyl ethers. Bridgehead radicals were also examined.
Copyright OwnerAmerican Chemical Society
Citation InformationGeorge A. Kraus and Yung Son Hon. "Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes" The Journal of Organic Chemistry Vol. 50 Iss. 23 (1985) p. 4605 - 4608
Available at: http://works.bepress.com/george_kraus/172/