Article
Cycloaddition reactions of bridgehead enones
The Journal of Organic Chemistry
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
4-1-1988
DOI
10.1021/jo00242a011
Abstract
The cycloaddition reactions of bridgehead enones derived in situ from ketones 8,9, and 10 with various dienes at 0 "C afford good yields of adducta. Even 1,1,3-trisubstituted dienes work well. The exclusive exo stereochemistry can be rationalized in terms of a stepwise mechanism involving ionic intermediates.
Copyright Owner
American Chemical Society
Copyright Date
1988
Language
en
File Format
application/pdf
Citation Information
George A. Kraus, Yung Son Hon, James Sy and Jeff Raggon. "Cycloaddition reactions of bridgehead enones" The Journal of Organic Chemistry Vol. 53 Iss. 7 (1988) p. 1397 - 1400 Available at: http://works.bepress.com/george_kraus/130/
Reprinted (adapted) with permission from The Journal of Organic Chemistry, 53(7); 1397-1400. Doi: 10.1021/jo00242a011. Copyright 1988 American Chemical Society.