Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexesInorganic Chemistry
Publication VersionPublished Version
AbstractMolecular models indicate that they should chelate to metals with the donor groups at 90° with respect to each other. From reactions of the diisocyano ligand DiNC, the following complexes with chelating DiNC ligands have been isolated: Cr(CO),(DiNC), Mo(CO),(DiNC), W(CO),(DiNC), MII(CO)~(D~NC)B~, CpFe(CO)(DiNC)+, and CpFe(CS)(DiNC)+. The characterization of these complexes demonstrates that DiNC can function as a chelating ligand despite its formation of a 13-member chelate ring.
Copyright OwnerAmerican Chemical Society
Citation InformationRobert J. Angelici, Michael H. Quick, George A. Kraus and Daniel T. Plummer. "Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexes" Inorganic Chemistry Vol. 21 Iss. 6 (1982) p. 2178 - 2184
Available at: http://works.bepress.com/george_kraus/109/