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Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexes
Inorganic Chemistry
  • Robert J. Angelici, Iowa State University
  • Michael H. Quick, Iowa State University
  • George A. Kraus, Iowa State University
  • Daniel T. Plummer, Iowa State University
Document Type
Article
Publication Version
Published Version
Publication Date
6-1-1982
DOI
10.1021/ic00136a009
Abstract

Molecular models indicate that they should chelate to metals with the donor groups at 90° with respect to each other. From reactions of the diisocyano ligand DiNC, the following complexes with chelating DiNC ligands have been isolated: Cr(CO),(DiNC), Mo(CO),(DiNC), W(CO),(DiNC), MII(CO)~(D~NC)B~, CpFe(CO)(DiNC)+, and CpFe(CS)(DiNC)+. The characterization of these complexes demonstrates that DiNC can function as a chelating ligand despite its formation of a 13-member chelate ring.

Comments

Reprinted (adapted) with permission from Inorganic Chemistry, 21(6); 2178-2184. Doi: 10.1021/ic00136a009. Copyright 1982 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
Robert J. Angelici, Michael H. Quick, George A. Kraus and Daniel T. Plummer. "Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexes" Inorganic Chemistry Vol. 21 Iss. 6 (1982) p. 2178 - 2184
Available at: http://works.bepress.com/george_kraus/109/