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Article
Electric-Dipole 4fN-4fN Transition Intensity Parametrizations for Lanthanides: Multiple Indistinguishable Parameter Sets and Multiple Local Minima
Journal of Alloys and Compounds
  • G. W. Burdick, Andrews University
  • R. L. Summerscales, Andrews University
  • S. M. Crooks, Andrews University
  • M. F. Reid, Andrews University
  • F. S. Richardson, Andrews University
Document Type
Article
Publication Date
5-24-2000
Keywords
  • Electric-dipole transitions,
  • Lanthanide ions,
  • Multiple indistinguishable parameter sets
Abstract

For most symmetries the standard parametrization of one-photon electric-dipole transitions between crystal-field levels of the 4f configuration of lanthanide ions gives the same predictions for several quite different parameter sets. An alternative parametrization scheme that provides separate parameters for each of the different polarization directions removes this anomaly. A second problem arises due to the fact that multiple local minima may fit the data nearly equally well. Through a detailed reexamination of the previously well-studied system NdODA, we examine and attempt to resolve this local minima problem. © 2000 Elsevier Science S.A. All rights reserved.

DOI
https://doi.org/10.1016/S0925-8388(00)00644-7
First Department
Physics
Citation Information
G. W. Burdick, R. L. Summerscales, S. M. Crooks, M. F. Reid, et al.. "Electric-Dipole 4fN-4fN Transition Intensity Parametrizations for Lanthanides: Multiple Indistinguishable Parameter Sets and Multiple Local Minima" Journal of Alloys and Compounds Vol. 303-304 (2000) p. 376 - 382
Available at: http://works.bepress.com/gary_burdick/90/