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Supercharged cations of benzene
Journal of Physical Chemistry (1985)
  • J R Appling, Georgia Institute of Technology - Main Campus
  • Gary W Burdick, Andrews University
  • M J Hayward, Georgia Institute of Technology - Main Campus
  • L E Abbey, Georgia Institute of Technology - Main Campus
  • Thomas F Moran, Georgia Institute of Technology - Main Campus
Abstract

Stable, supercharged benzene ions produced in electron impact ionization have been observed by techniques of collisional mass spectrometry in which single electron transfer reactions of incident C6H6 n+ ions at kiloelectronvolt energies give rise to stable C6H6 (n-1)+ product ions. Semiempirical SCF-MO calculations employed for the computation of C6H6 n+ structures indicate that geometry optimized minimum energy C6H6 n+ cyclic ions exhibit a progression of elongation and expansion as n increases. Structural and energetic data have been obtained for the n = 1 to 6 charge states of benzene.

Disciplines
Publication Date
1985
Citation Information
J R Appling, Gary W Burdick, M J Hayward, L E Abbey, et al.. "Supercharged cations of benzene" Journal of Physical Chemistry Vol. 89 Iss. 1 (1985)
Available at: http://works.bepress.com/gary_burdick/39/