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An Analysis of the Mössbauer Spectral Hyperfine Parameters of RFe₁₁Ti and RFe₁₁TiH, Where R Is a Rare-Earth Element
Journal of Physics: Condensed Matter
  • Cristina Piquer
  • Fernande Grandjean, Missouri University of Science and Technology
  • Olivier Isnard
  • Gary J. Long, Missouri University of Science and Technology
Abstract

The Mössbauer spectra of CeFe11Ti and CeFe11TiH obtained between 4.2 and 295 K are analysed in terms of the model used to analyse the spectra of the RFe11Ti and RFe11TiH compounds, where R is Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er and Lu. The hyperfine parameters obtained with a consistent model that considers both the easy magnetization direction and the titanium preferential site occupancy are discussed as a function of rare-earth atomic number, temperature and hydrogen content. The average hyperfine fields in the RFe11Ti and RFe11TiH compounds are described with a two-sublattice model in which the iron sublattice contributions coincide with the fields observed in LuFe 11Ti and LuFe11TiH, respectively. In both series, the rare-earth sublattice contributes a transferred field which occurs as a result of indirect exchange between the rare-earth 4f and iron 3d electrons and depends on the nature of the rare-earth element. The increase in average hyperfine field and isomer shift upon hydrogenation of the RFe11Ti compounds results from the unit-cell expansion upon hydride formation. The observed average quadrupole shift is closely related to the magnetic anisotropy exhibited by each compound.

Department(s)
Chemistry
Sponsor(s)
French National Center for Scientific Research
National Science Foundation of Belgium
Belgium. Ministry of the French Speaking Community
National Science Foundation (U.S.)
University of Li`ege
Keywords and Phrases
  • Isomers,
  • Magnetic Anisotropy,
  • Magnetization,
  • Mathematical Models,
  • Mössbauer Spectroscopy,
  • Hyperfine Parameters,
  • Rare Earth Atomic Numbers,
  • Rare-earth Sublattice,
  • Rare Earth Elements
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2006 Institute of Physics - IOP Publishing, All rights reserved.
Publication Date
1-1-2006
Publication Date
01 Jan 2006
Disciplines
Citation Information
Cristina Piquer, Fernande Grandjean, Olivier Isnard and Gary J. Long. "An Analysis of the Mössbauer Spectral Hyperfine Parameters of RFe₁₁Ti and RFe₁₁TiH, Where R Is a Rare-Earth Element" Journal of Physics: Condensed Matter Vol. 18 Iss. 1 (2006) p. 205 - 219 ISSN: 0953-8984
Available at: http://works.bepress.com/gary-long/91/