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Article
Thermodynamic Calculation of Work for Some Irreversible Processes
Journal of Chemical Education
  • Gary L. Bertrand, Missouri University of Science and Technology
Abstract

The idea that thermodynamic work depends on the speed of the process is not new. The concept of reversible process carried out in a series of infinitesimal steps suggests an extremely slow process. It is generally recognized that the effective voltage of a battery decreases with increasing current, with the reversible voltage represented by the value measured at zero current. The same principle can be applied to mechanical processes. A definition of mechanical work and its application to a system confined by a piston are given.

Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2005 American Chemical Society (ACS), All rights reserved.
Publication Date
1-1-2005
Publication Date
01 Jan 2005
Disciplines
Citation Information
Gary L. Bertrand. "Thermodynamic Calculation of Work for Some Irreversible Processes" Journal of Chemical Education (2005) ISSN: 0021-9584
Available at: http://works.bepress.com/gary-bertrand/62/