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Article
Thermochemical Investigations of Nearly Idela Binary Solvents II
Journal of Solution Chemistry
  • Thomas E. Burchfield
  • Gary L. Bertrand, Missouri University of Science and Technology
Alternative Title
Standard heats of solution in systems of nonspecific interactions
Abstract

Standard heats of solution at 25°C are reported for squalane in mixtures of n-heptane + iso-octane and in binary mixtures of chloroform, carbon tetrachloride, and cyclohexane; for cyclohexane in chloroform + carbon tetrachloride; and for chloroform in carbon tetrachloride + cyclohexane. General equations based on simple mixing models are developed for the excess thermodynamic properties of a solute at infinite dilution in a binary solvent. For the systems studied, mixing equations based on volume fractions give better agreement than those based on mole fractions, and the agreement is further improved by the use of weighting factors based on the properties of the solute + solvent binary systems. © 1975 Plenum Publishing Corporation.

Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1975 Springer Verlag, All rights reserved.
Publication Date
1-1-1975
Publication Date
01 Jan 1975
Disciplines
Citation Information
Thomas E. Burchfield and Gary L. Bertrand. "Thermochemical Investigations of Nearly Idela Binary Solvents II" Journal of Solution Chemistry (1975) ISSN: 0095-9782
Available at: http://works.bepress.com/gary-bertrand/54/