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Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.
Dalton transactions
  • Lars Lauterbach
  • Leland B Gee
  • Vladimir Pelmenschikov
  • Francis Jenney, Philadelphia College of Osteopathic Medicine
  • Saeed Kamali
  • Yoshitaka Yoda
  • Michael W W Adams
  • Stephen P Cramer
Document Type
Article
Publication Date
4-11-2016
Abstract

The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.

Comments

This article was published in Dalton Transactions, 2016.

The published version is available at http://dx.doi.org/10.1039/C5DT04760A

Copyright © 2016 Royal Society of Chemistry

Citation Information
Lars Lauterbach, Leland B Gee, Vladimir Pelmenschikov, Francis Jenney, et al.. "Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses." Dalton transactions (2016)
Available at: http://works.bepress.com/francis_jenney/78/