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Article
Observation of the Fe-CN and Fe-CO vibrations in the active site of [NiFe] hydrogenase by nuclear resonance vibrational spectroscopy
Angewandte Chemie - International Edition
  • S. Kamali
  • H. Wang
  • D. Mitra
  • H. Ogata
  • W. Lubitz
  • B. C. Manor
  • T. B. Rauchfuss
  • D. Byrne
  • Francis E. Jenney, Jr., Philadelphia College of Osteopathic Medicine
  • et al.
Document Type
Article
Publication Date
1-1-2013
Disciplines
Abstract
Nuclear inelastic scattering of 57Fe labeled [NiFe] hydrogenase is shown to give information on different states of the enzyme. It was thus possible to detect and assign Fe-CO and Fe-CN bending and stretching vibrations of the active site outside the spectral range of the Fe-S cluster normal modes. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Comments

This article was published in Angewandte Chemie - International Edition, Volume 52, Issue 2, Pages 724-728.

The published version is available at http://dx.doi.org/10.1002/anie.201204616.

Copyright © 2013 Wiley.

Citation Information
S. Kamali, H. Wang, D. Mitra, H. Ogata, et al.. "Observation of the Fe-CN and Fe-CO vibrations in the active site of [NiFe] hydrogenase by nuclear resonance vibrational spectroscopy" Angewandte Chemie - International Edition Vol. 52 (2013) p. 724 - 728
Available at: http://works.bepress.com/francis_jenney/60/