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Redox Stable Solid Oxide Fuel Cells with Ni-YSZ Cermet Anodes Prepared by Polymeric Precursor Infiltration
Journal of The Electrochemical Society
  • Aligul Buyukaksoy
  • Vladimir Petrovsky
  • Fatih Dogan, Missouri University of Science and Technology
Abstract

Redox stable SOFCs with Ni-YSZ cermet anodes were developed for electrolyte supported design (electrolyte thickness: 170 μm). Redox stable Ni-YSZ anode was prepared by infiltrating polymeric NiO precursor into pre-sintered porous YSZ layer (∼10 μm thick) followed by reduction ex situ. Polymeric precursor infiltration technique yielded a Ni-YSZ cermet microstructure with nanosized Ni particles coating the surface of porous YSZ. Low temperature processing of nanostructured Ni-YSZ cermet resulted in the reduction of internal stresses between Ni/NiO coating and YSZ skeleton during the redox cycling process. Electrolyte supported SOFC prepared with Ni-infiltrated anode showed a power density of ∼0.315 Watt.cm−2 and a highly redox stable anode (reduction of power density less than 1% after 15 redox cycles) in humidified forming gas (10%H2-90%Ar).

Department(s)
Materials Science and Engineering
Keywords and Phrases
  • Fuel Cells,
  • Energy Conversion
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2012 The Electrochemical Society (ECS), All rights reserved.
Publication Date
1-1-2012
Publication Date
01 Jan 2012
Citation Information
Aligul Buyukaksoy, Vladimir Petrovsky and Fatih Dogan. "Redox Stable Solid Oxide Fuel Cells with Ni-YSZ Cermet Anodes Prepared by Polymeric Precursor Infiltration" Journal of The Electrochemical Society (2012) ISSN: 0013-4651
Available at: http://works.bepress.com/fatih-dogan/161/