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Article
New Low to Medium Temperature Electrolyte Separation Method and System for Alkaline Water Electrolysis
ECS Transactions
  • J. L. Hartvigsen
  • Joseph D. Smith, Missouri University of Science and Technology
  • Fatih Dogan, Missouri University of Science and Technology
Abstract

A new electrolysis method of maintaining product gas separation by using fluid flow perpendicularly through porous electrodes rather than using a gas impermeable membrane has been developed. This eliminates the need for any type of membrane. Eliminating the need for a membrane in alkaline electrolysis allows the device to operate at temperatures above 120°C, where most ion conducting membranes would degrade and fail. Operating at higher temperatures reduces the anode and cathode overpotentials substantially. The reduction in overpotentials allows non-platinum group metals to be used, while increasing the electrical efficiency at comparable current densities.

Meeting Name
14th International Symposium on Solid Oxide Fuel Cells, SOFC 2015, held as part of the Electrochemical Society, ECS Conference on Electrochemical Energy Conversion and Storage (2015: Jul. 26-31, Glasgow, UK)
Department(s)
Chemical and Biochemical Engineering
Second Department
Materials Science and Engineering
Keywords and Phrases
  • Electrodes,
  • Electrolysis,
  • Electrolytes,
  • Energy conversion,
  • Flow of fluids,
  • Fuel storage,
  • Hydrogen,
  • Solid oxide fuel cells (SOFC),
  • Temperature,
  • Alkaline electrolysis,
  • Alkaline water electrolysis,
  • Electrical efficiency,
  • Ion-conducting membranes,
  • Medium temperature,
  • Over potential,
  • Porous electrodes,
  • Separation methods,
  • Gas permeable membranes
International Standard Book Number (ISBN)
978-1607685395
Document Type
Article - Conference proceedings
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2015 The Electrochemical Society (ECS), All rights reserved.
Publication Date
7-31-2015
Publication Date
31 Jul 2015
Citation Information
J. L. Hartvigsen, Joseph D. Smith and Fatih Dogan. "New Low to Medium Temperature Electrolyte Separation Method and System for Alkaline Water Electrolysis" ECS Transactions Vol. 68 Iss. 3 (2015) p. 133 - 137 ISSN: 1938-5862
Available at: http://works.bepress.com/fatih-dogan/131/