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Article
Synthesis and Formation Mechanism of CuInS2 Nanocrystals with a Tunable Phase
CrystEngComm
  • Chao Yu
  • Linlin Zhang
  • Long Tian
  • Dan Liu
  • Fanglin Chen, University of South Carolina - Columbia
  • Cheng Wang
Publication Date
11-7-2014
Document Type
Article
Abstract
Chalcopyrite CuInS2 (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl3 instead of In(NO3)3 as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of organic dye were also compared.
Citation Information
Chao Yu, Linlin Zhang, Long Tian, Dan Liu, et al.. "Synthesis and Formation Mechanism of CuInS2 Nanocrystals with a Tunable Phase" CrystEngComm Vol. 16 Iss. 481 (2014) p. 9596 - 9602
Available at: http://works.bepress.com/fanglin_chen/96/