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Article
Acetyl nitrate mediated conversion of methyl ketones to diverse carboxylic acid derivativesNo Title
Organic & Biomolecular Chemistry (2021)
  • Joseph N. Capilato, Rowan University
  • Peter J. Pellegrinelli, Rowan University
  • Josephine Bernard, Rowan University
  • Logan Schnorbus, Rowan University
  • Shane Philippi
  • Joseph Mattiucci, Rowan University
  • Erik Hoy, Rowan University
  • Dr. Lark Perez, Rowan University
Abstract
The development of a novel acetyl nitrate mediated oxidative conversion of methyl ketones to carboxylic acid derivatives is described. By analogy to the haloform reaction and supported by experimental and computational investigation we propose a mechanism for this transformation.
Publication Date
Spring May 26, 2021
DOI
https://doi.org/10.1039/D1OB00786F
Citation Information
Joseph N. Capilato, Peter J. Pellegrinelli, Josephine Bernard, Logan Schnorbus, et al.. "Acetyl nitrate mediated conversion of methyl ketones to diverse carboxylic acid derivativesNo Title" Organic & Biomolecular Chemistry Vol. 19 (2021) p. 5298 - 5302
Available at: http://works.bepress.com/erik-hoy/13/