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Determination of the absorption coefficient of chromophoric dissolved organic matter from underway spectrophotometry
Optics Express
  • Giorgio Dall’Olmo, Plymouth Marine Laboratory
  • Robert J. W. Brewin, Plymouth Marine Laboratory
  • Francesco Nencioli, Plymouth Marine Laboratory
  • Emanuele Organelli, Plymouth Marine Laboratory
  • Ina Lefering, University of Strathclyde
  • David McKee, University of Strathclyde
  • Rüdiger Röttgers, Helmholtz-Zentrum Geesthacht - Zentrum für Material- und Küstenforschung GmbH
  • Catherine Mitchell, Bigelow Laboratory for Ocean Sciences
  • Emmanuel Boss, University of Maine
  • Annick Bricaud, Sorbonne Universite
  • Gavin Tilstone, Plymouth Marine Laboratory
Document Type
Article
Rights and Access Note
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Publication Date
11-27-2017
Abstract/ Summary

Measurements of the absorption coefficient of chromophoric dissolved organic matter (ay) are needed to validate existing ocean-color algorithms. In the surface open ocean, these measurements are challenging because of low ay values. Yet, existing global datasets demonstrate that ay could contribute between 30% to 50% of the total absorption budget in the 400-450 nm spectral range, thus making accurate measurement of ay essential to constrain these uncertainties. In this study, we present a simple way of determining ay using a commercially-available in-situ spectrophotometer operated in underway mode. The obtained ay values were validated using independent collocated measurements. The method is simple to implement, can provide measurements with very high spatio-temporal resolution, and has an accuracy of about 0.0004 m−1 and a precision of about 0.0025 m−1 when compared to independent data (at 440 nm). The only limitation for using this method at sea is that it relies on the availability of relatively large volumes of ultrapure water. Despite this limitation, the method can deliver the ay data needed for validating and assessing uncertainties in ocean-colour algorithms.

Citation/Publisher Attribution
Dall'Olmo G., R. J. W. Brewin, F.Nencioli, E. Organelli, I. Lefering, D. McKee, R. Rottgers, C. Mitchell, E. Boss, A. Bricaud, and G. Tilstone , 2017. Determination of the absorption coefficient of chromophoric dissolved organic matter from underway spectrophotometry. Optics Express, 25, 24, https://doi.org/10.1364/OE.25.0A1079
Publisher Statement
©2017 Optical Society of America
DOI
10.1364/OE.25.0A1079
Version
publisher's version of the published document
Citation Information
Giorgio Dall’Olmo, Robert J. W. Brewin, Francesco Nencioli, Emanuele Organelli, et al.. "Determination of the absorption coefficient of chromophoric dissolved organic matter from underway spectrophotometry" Optics Express Vol. 25 Iss. 24 (2017) p. A1079 - A1095
Available at: http://works.bepress.com/emmanuel_boss/42/