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Large low-energy oscillator strength for Ce 4f electrons in the solid state
Physical Review B
  • Kwang Joo Kim, Iowa State University
  • Bruce N. Harmon, Iowa State University
  • David W. Lynch, Iowa State University
  • Dale D. Koelling, Argonne National Laboratory
Document Type
Article
Publication Date
10-1-1991
DOI
10.1103/PhysRevB.44.8526
Abstract
The conductivity sum rule applied to LaSn3, CeSn3, LaB6, and CeB6 between 1.5 and 4.35 eV shows that there is approximately one more electron contributing to the optical conductivity of the Ce compounds than to that of the analogous La compounds. From the data and band calculations we conclude that about 0.5 Ce 4f electron per atom contributes as initial states for CeSn3 in the above energy range, and about half that number of 4f electrons serve as initial states in LaSn3. This shift of oscillator strength from higher energies for atoms to lower energies for solids is attributed to hybridization. Much of the remaining Ce-La difference is from transitions to p-like final states, which are reduced in the La compounds due to hybridization with unoccupied 4f states.
Comments

This article is from Physical Review B 44 (1991): 8526, doi:10.1103/PhysRevB.44.8526. Posted with permission.

Copyright Owner
The American Physical Society
Language
en
File Format
application/pdf
Citation Information
Kwang Joo Kim, Bruce N. Harmon, David W. Lynch and Dale D. Koelling. "Large low-energy oscillator strength for Ce 4f electrons in the solid state" Physical Review B Vol. 44 Iss. 16 (1991) p. 8526 - 8528
Available at: http://works.bepress.com/david_lynch1/36/