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Article
Hydrogen Incorporation and Diffusivity in Plasma-Exposed Bulk ZnO
Applied Physics Letters
  • K. Ip
  • M. E. Overberg
  • Y. W. Heo
  • D. P. Norton
  • S. J. Pearton
  • C. E. Stutz
  • B. Luo
  • F. Ren
  • David C. Look, Wright State University - Main Campus
  • J. M. Zavada
Document Type
Article
Publication Date
1-1-2003
Abstract

Hydrogen incorporation depths of >25 μm were obtained in bulk, single-crystal ZnO during exposure to 2H plasmas for 0.5 h at 300 °C, producing an estimated diffusivity of ∼ 8×10−10 cm2/V⋅s at this temperature. The activation energy for diffusion was 0.17±0.12 eV, indicating an interstitial mechanism. Subsequent annealing at 500–600 °C was sufficient to evolve all of the hydrogen out of the ZnO, at least to the sensitivity of secondary ion mass spectrometry (<5×1015 cm−3). The thermal stability of hydrogen retention is slightly greater when the hydrogen is incorporated by direct implantation relative to plasma exposure, due to trapping at residual damage in the former case.

Comments

Copyright © 2003, American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 82.3, and may be found at http://apl.aip.org/resource/1/applab/v82/i3/p385_s1

DOI
10.1063/1.1539927
Citation Information
K. Ip, M. E. Overberg, Y. W. Heo, D. P. Norton, et al.. "Hydrogen Incorporation and Diffusivity in Plasma-Exposed Bulk ZnO" Applied Physics Letters Vol. 82 Iss. 3 (2003) p. 385 - 387 ISSN: 0003-6951
Available at: http://works.bepress.com/david_look/160/