Article
Carbon-13 Nuclear Magnetic Resonance Studies of Trans-Diacido(tetraamine) Cobalt(III) Complexes
Inorganic Chemistry
Document Type
Article
Publication Date
6-1-1982
Abstract
Carbon-1 3 nuclear magnetic resonance spectra of a series of trans-diacido( 1 ,lO-diamino-4,7-dia~aadecane)cobalt(III) complexes (truns-Co(3,2,3-tet)X2, X = Br-, C1-, N3-, NH,, NO2-, OAc) and trans-diacido( 1,9-diamino-3,7-diazanonane)cobalt(III) complexes (trans-Co(2,3,2-tet)X2, X = C1-, GlyH, -OAc, NH,, NO2-) will be discussed. The "C chemical shift is found to be linearly dependent on the ligand field strength (estimated from the electronic spectrum) of the axial ligands (X). The shielding of selected carbon atoms within the tetraamine ligand, which has been attributed to the central metal ion, increases with increasing axial ligand field strength.
Inclusive pages
2223–2226
ISBN/ISSN
0020-1669
Publisher
American Chemical Society
Peer Reviewed
Yes
Disciplines
- Analytical Chemistry,
- Biochemical Phenomena, Metabolism, and Nutrition,
- Chemical and Pharmacologic Phenomena,
- Chemistry,
- Environmental Chemistry,
- Inorganic Chemistry,
- Materials Chemistry,
- Medical Biochemistry,
- Medicinal-Pharmaceutical Chemistry,
- Organic Chemistry,
- Other Chemistry and
- Physical Chemistry
Citation Information
George R. Brubaker and David W. Johnson. "Carbon-13 Nuclear Magnetic Resonance Studies of Trans-Diacido(tetraamine) Cobalt(III) Complexes" Inorganic Chemistry Vol. 21 Iss. 6 (1982) Available at: http://works.bepress.com/david_johnson/53/