Article
Synthesis of Rhodium(III), Iridium(III) and Osmium(III) Complexes with tris(2-Aminoethane-thiolato)cobalt(III)
Inorganica Chimica Acta
Document Type
Article
Publication Date
12-1-1988
Abstract
Polynuclear sulfur bridged complexes where the neutral complex tris(2-aminoethanethiolato)cobalt(III) acts as a tridentate ligand to rhodium(III), iridium(III) and osmium(III) have been prepared. These complexes have been characterized by electronic spectroscopy, vibrational spectroscopy and nuclear magnetic resonance spectroscopy. Along with the previously prepared complexes of iron(III), ruthenium(III) and cobalt(III), these complexes form two series of complexes with the group 8 and group 9 elements from all three transition series.
Inclusive pages
221-224
ISBN/ISSN
0020-1693
Publisher
Elsevier
Peer Reviewed
Yes
Disciplines
- Analytical Chemistry,
- Biochemical Phenomena, Metabolism, and Nutrition,
- Chemical and Pharmacologic Phenomena,
- Chemistry,
- Environmental Chemistry,
- Inorganic Chemistry,
- Materials Chemistry,
- Medical Biochemistry,
- Medicinal-Pharmaceutical Chemistry,
- Organic Chemistry,
- Other Chemistry and
- Physical Chemistry
Citation Information
David W. Johnson and Timothy R. Brewer. "Synthesis of Rhodium(III), Iridium(III) and Osmium(III) Complexes with tris(2-Aminoethane-thiolato)cobalt(III)" Inorganica Chimica Acta Vol. 154 Iss. 2 (1988) Available at: http://works.bepress.com/david_johnson/44/
The authors wish to thank the University of Dayton Research Council for their support in the form of a summer fellowship for David W. Johnson and assistance in the purchase of equipment used in this study. The authors also wish to acknowledge partial support from the Ohio Board of Regents Challenge Grant program for the purchase of the NMR instrument used in this study.