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Selected Works of David J. R. Brook
Article
Valence Tautomerism in a Cobalt-Verdazyl Coordination Compound
Chemical Communications (2020)
  • Connor Fleming, San Jose State University
  • Dorothy Chung, San Jose State University
  • Servando Ponce, San Jose State University
  • David J R Brook, San Jose State University
  • Jeffrey Daros, San Jose State University
  • Raja R Das, Phenikaa University
  • Andrew Ożarowski, Florida State University
  • Sebastian A Stoian, University of Idaho
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Abstract
Coordination of 1-isopropyl-3,5-dipyridyl-6-oxoverdazyl to cobalt results in a dication best described in the solid state as a high spin cobalt(ii) ion coordinated to two radical ligands with an S = 3/2 ground state. On dissolution in acetonitrile, the cobalt(ii) form equilibrates with a cobalt(iii) valence tautomer with an S = 1/2 ground state. © 2020 The Royal Society of Chemistry.
Keywords
  • Cobalt compounds,
  • Ground state,
  • Dications
Disciplines
Publication Date
March 26, 2020
DOI
10.1039/d0cc01770a
Publisher Statement
SJSU users: Use the following link to login and access this article via SJSU databases.
Citation Information
Connor Fleming, Dorothy Chung, Servando Ponce, David J R Brook, et al.. "Valence Tautomerism in a Cobalt-Verdazyl Coordination Compound" Chemical Communications (2020)
Available at: http://works.bepress.com/david_brook/33/