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Selected Works of David J. R. Brook
Article
Synthesis and Structure of di-μ-bromo-bis[(1,5-dimethyl-3-(2’-pyridyl)-6-oxoverdazyl) copper(I)]
Journal of the Chemical Society, Dalton Transactions (2000)
  • David J R Brook, San Jose State University
  • S Fornell, University of Detroit Mercy
  • B Noll, University of Colorado at Boulder
  • G Yee, University of Colorado at Boulder
  • T H Koch, University of Colorado at Boulder
Link
Abstract
Reaction of the verdazyl precursor 1,4,5,6-tetrahydro-2,4-dimethyl-6-(2′-pyridyl)-1,2,4,5-tetrazin-3(2H)-one (pvdH3) with oxygen and copper(I) bromide in acetonitrile results in precipitation of the crystalline diradical di-μ-bromo-bis[(1,5-dimethyl-6-oxo-3-(2-pyridyl)verdazyl)copper(I)]. The solid shows a slightly anisotropic ESR spectrum and magnetic susceptibility measurements indicate weak antiferromagnetic exchange between the free radicals, consistent with the assignment as a copper(I) ion coordinated to a free radical.
Disciplines
Publication Date
2000
Publisher Statement
SJSU users: use the following link to login and access the article via SJSU databases
Citation Information
David J R Brook, S Fornell, B Noll, G Yee, et al.. "Synthesis and Structure of di-μ-bromo-bis[(1,5-dimethyl-3-(2’-pyridyl)-6-oxoverdazyl) copper(I)]" Journal of the Chemical Society, Dalton Transactions (2000)
Available at: http://works.bepress.com/david_brook/13/