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Article
Measurement of Ring Strain Using Butanols: A Physical Chemistry Lab Experiment
Journal of Chemical Education
  • William R. Martin, Cleveland State University
  • Ada S. Davidson, Cleveland State University
  • David W. Ball, Cleveland State University
Document Type
Article
Publication Date
1-1-2016
Disciplines
Abstract

In this article, a bomb calorimeter experiment and subsequent calculations aimed at determining the strain energy of the cyclobutane backbone are described. Students use several butanol isomers instead of the parent hydrocarbons, and they manipulate liquids instead of gases, which makes the experiment much easier to perform. Experiments show that the estimated strain energy is reasonably close to literature values for cyclobutane.

DOI
10.1021/acs.jchemed.5b00651
Citation Information
Martin, W. R.; Davidson, A. S.; Ball, D. W. Measurement of Ring Strain Using Butanols: A Physical Chemistry Lab Experiment J. Chem. Educ. 2016, 93, 1652 - 1656.