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Article
Ultra-High Temperature Oxidation of a Hafnium Carbide-Based Solid Solution Ceramic Composite
Corrosion Science
  • David W. Lipke, Missouri University of Science and Technology
  • Sergey V. Ushakov
  • Alexandra Navrotsky
  • Wesley P. Hoffman
Abstract

Hafnium carbide-based solid solution ceramics with yttria additions were consolidated via hot pressing utilizing chromium carbide as a transient liquid sintering agent. Selected samples were oxidized at temperatures exceeding 2200. °C under high velocity airflow to determine their potential for service in ultra-high temperature environments. Cross-sectional examination revealed a complex multi-layer scale comprising a highly porous exterior region, a dense multi-phase interior region, and an oxygen- and carbon-containing interlayer consisting of nanocrystalline graphite in an amorphous or nanocrystalline oxide matrix. Outward diffusion of mobile cations is speculated to play an important role in establishing the observed scale morphology.

Department(s)
Materials Science and Engineering
Comments
This research was performed while the author (D.W.L.) held a National Research Council Associateship Award at the Air Force Research Laboratory, Edwards AFB, CA 93524 USA.
Keywords and Phrases
  • A. Ceramic,
  • C. High temperature corrosion,
  • C. Oxidation
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2014 Elsevier Ltd., All rights reserved.
Publication Date
3-1-2014
Publication Date
01 Mar 2014
Citation Information
David W. Lipke, Sergey V. Ushakov, Alexandra Navrotsky and Wesley P. Hoffman. "Ultra-High Temperature Oxidation of a Hafnium Carbide-Based Solid Solution Ceramic Composite" Corrosion Science Vol. 80 (2014) p. 402 - 407 ISSN: 0010-938X
Available at: http://works.bepress.com/david-lipke/2/