Skip to main content
Article
Oxidation Investigation of NBG-18 Nuclear-Grade Graphite
Transactions of the American Nuclear Society
  • Joshua Kane, Boise State University
  • C. Karthik, Boise State University
  • Rick Ubic, Boise State University
  • William E. Windes, Center for Advanced Energy Studies
  • Darryl P. Butt, Boise State University
Document Type
Conference Proceeding
Publication Date
6-24-2012
Abstract

The oxidation kinetics of NBG-18 nuclear graphite was investigated between 500 and 775°C with oxygen partial pressures ranging from 10 to 40 kPa. Using a phenomenological shrinking-core model, reaction rates normalized to the reactive surface area were determined. In addition, a more rigorous, mechanism-based model is proposed for the reaction rate of nuclear graphites based on observed spill-over of the carbon-oxygen surface intermediate onto the graphite basal plane. This mechanistic model suggests the reaction is controlled simultaneously by the dissociative chemisorption of oxygen and the desorption of reactive surface intermediates to form CO(g) and CO2(g). The activation energies for these processes were approximated as180±10, 260±10 and 190±10 kJ/mol, respectively.

Citation Information
Joshua Kane, C. Karthik, Rick Ubic, William E. Windes, et al.. "Oxidation Investigation of NBG-18 Nuclear-Grade Graphite" Transactions of the American Nuclear Society (2012)
Available at: http://works.bepress.com/darryl_butt/40/