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Article
Tellurium Thermodynamics in Austenitic Iron
Canadian Metallurgical Quarterly
  • Govind Sharan Gupta
  • D. G. C. Robertson, Missouri University of Science and Technology
  • Mark E. Schlesinger, Missouri University of Science and Technology
Editor(s)
McDermid, J. R.
Abstract

A two-zone furnace arrangement was used to determine the solubility of tellurium vapour in γ-iron foils at 1273 and 1548 K. Liquid tellurium held at a lower temperature generated Te (g) and Te2 (g) at a known partial pressure which was equilibrated with foils held at a higher temperature. Knowledge of the two temperatures allowed the calculation of the activity of tellurium with respect to the solid reference state. Analysis of the equilibrated foils allowed the calculation of the infinite dilution activity coefficient of tellurium which is expressed as a function of temperature.

Department(s)
Materials Science and Engineering
Keywords and Phrases
  • Austenite,
  • Iron,
  • Metal foil,
  • Partial pressure,
  • Solubility,
  • Thermodynamics,
  • Vapors,
  • Austenitic iron,
  • Dilution activity coefficients,
  • Tellurium thermodynamics,
  • Two-zone furnace arrangement,
  • Tellurium
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2005 Maney Publishing, All rights reserved.
Publication Date
1-1-2005
Publication Date
01 Jan 2005
Citation Information
Govind Sharan Gupta, D. G. C. Robertson and Mark E. Schlesinger. "Tellurium Thermodynamics in Austenitic Iron" Canadian Metallurgical Quarterly Vol. 44 Iss. 3 (2005) p. 351 - 356 ISSN: 0008-4433
Available at: http://works.bepress.com/d-robertson/80/