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Article
Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent
ACS Catalysis
  • Yomaira J. Pagan-Torres, University of Wisconsin - Madison
  • Tianfu Wang, Iowa State University
  • Jean Marcel R. Gallo, University of Wisconsin - Madison
  • Brent H. Shanks, Iowa State University
  • James A. Dumesic, University of Wisconsin - Madison
Document Type
Article
Publication Version
Published Version
Publication Date
1-1-2012
DOI
10.1021/cs300192z
Abstract
We report the catalytic conversion of glucose in high yields (62%) to 5-hydroxymethylfurfural (HMF), a versatile platform chemical. The reaction system consists of a Lewis acid metal chloride (e.g., AlCl 3) and a Bronsted acid (HCl) in a biphasic reactor consisting of water and an alkylphenol compound (2-sec-butylphenol) as the organic phase. The conversion of glucose in the presence of Lewis and Bronsted acidity proceeds through a tandem pathway involving isomerization of glucose to fructose, followed by dehydration of fructose to HMF. The organic phase extracts 97% of the HMF produced, while both acid catalysts remain in the aqueous phase.
Comments

Reprinted (adapted) with permission from ACS Catalysis 2 (2012): 930, doi: 10.1021/cs300192z. Copyright 2012 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
Date Available
2015-03-11
File Format
application/pdf
Citation Information
Yomaira J. Pagan-Torres, Tianfu Wang, Jean Marcel R. Gallo, Brent H. Shanks, et al.. "Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent" ACS Catalysis Vol. 2 Iss. 6 (2012) p. 930 - 934
Available at: http://works.bepress.com/brent_shanks/19/