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Sulfated zirconia modified SBA-15 catalysts for cellobiose hydrolysis
Catalysis Letters
  • Volkan Degirmenci, Middle East Technical University
  • Deniz Uner, Middle East Technical University
  • Basak Cinlar, Iowa State University
  • Brent H. Shanks, Iowa State University
  • Aysen Yilmaz, Middle East Technical University
  • Rutget A. van Santen, Eindhoven University of Technology
  • Emiel J. M. Hensen, Eindhoven University of Technology
Document Type
Article
Publication Version
Published Version
Publication Date
1-1-2010
DOI
10.1007/s10562-010-0466-1
Abstract
Zirconia modified SBA-15 becomes a very active catalyst for the selective hydrolysis of cellobiose to glucose after sulfation. Spectroscopic investigations indicate the presence of Brønsted acid sites with similar properties to those present in conventional sulfated zirconia. Indications are found that the sulfate groups attached to zirconia interact with silanol groups of SBA-15. The catalytic activity in cellobiose hydrolysis correlates well with results for temperature-programmed decomposition of i-propylamine for a range of sulfated ZrO2/SBA-15 catalysts. A glucose yield of 60% during cellobiose hydrolysis at a reaction time of 90 min at 160° C is obtained.
Comments

This is an article from Catalysis Letters 141 (2011): 33, doi: 10.1007/s10562-010-0466-1. Posted with permission.

Rights
Copyright 2010 V. Degirmenci et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright Owner
V. Degirmenci et al
Language
en
Date Available
2015-03-11
File Format
application/pdf
Citation Information
Volkan Degirmenci, Deniz Uner, Basak Cinlar, Brent H. Shanks, et al.. "Sulfated zirconia modified SBA-15 catalysts for cellobiose hydrolysis" Catalysis Letters Vol. 141 Iss. 1 (2010) p. 33 - 42
Available at: http://works.bepress.com/brent_shanks/12/