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Article
A radical spin on viologen polymers: organic spin crossover materials in water
Chemical Communications
  • Mark J. Juetten, Iowa State University
  • Alexander T. Buck, Iowa State University
  • Arthur H. Winter, Iowa State University
Document Type
Article
Publication Version
Accepted Manuscript
Publication Date
1-1-2015
DOI
10.1039/C4CC07119K
Abstract

A polymer containing viologen radical cation monomer units is shown to reversibly switch between paramagnetic and diamagnetic states via non-covalent host–guest interactions or temperature control in water. Cycling between diamagnetic and paramagnetic forms is accompanied by changes in optical and magnetic properties.

Comments

This is a manuscript of an article published as Juetten, Mark J., Alexander T. Buck, and Arthur H. Winter. "A radical spin on viologen polymers: organic spin crossover materials in water." Chemical Communications 51, no. 25 (2015): 5516-5519. doi: 10.1039/C4CC07119K. Posted with permission.

Copyright Owner
The Royal Society of Chemistry
Language
en
File Format
application/pdf
Citation Information
Mark J. Juetten, Alexander T. Buck and Arthur H. Winter. "A radical spin on viologen polymers: organic spin crossover materials in water" Chemical Communications Vol. 51 Iss. 25 (2015) p. 5516 - 5519
Available at: http://works.bepress.com/arthur_winter/27/