We report on the first measurement of the F2 structure function of the neutron from the semi-inclusive scattering of electrons from deuterium, with low-momentum protons detected in the backward hemisphere. Restricting the momentum of the spectator protons to <100  MeV/c and their angles to > 100° relative to the momentum transfer allows an interpretation of the process in terms of scattering from nearly on-shell neutrons. The Fn2 data collected cover the nucleon-resonance and deep-inelastic regions over a wide range of Bjorken x for 0.65