Skip to main content
Article
Molecular Wires Self-Assembled on a Graphite Surface
Langmuir (2009)
  • Andreas Riemann, Western Washington University
  • Brittany Nelson
Abstract
We report a scanning tunneling microscopy study of the amino acid L-methionine on highly ordered pyrolytic graphite deposited under ambient conditions. Our experiments demonstrate the ability of L-methionine to form highly regular structures on the surface of the graphite template. By means of self-assembly, the amino acid arranges itself into an array of molecular wires, i.e., well-ordered stripes of uniform width and separation. The spacing of these wires can be controlled with the deposition amount of the amino acid, whereas the width stays constant. The width of the wires is determined by two methionine molecules arranged with their carboxyl group facing each other. The regular separation of individual wires suggest a long-range interaction among them. Molecular mechanics calculations are used to compare the experimental results with a basic model for the methionine configuration on the surface. A model for the adsorption geometry of methionine on graphite is presented.
Publication Date
2009
Publisher Statement
Langmuir, 2009, 25 (8), pp 4522–4525 DOI: 10.1021/la803867w Publication Date (Web): March 4, 2009 Copyright © 2009 American Chemical Society
Citation Information
Andreas Riemann and Brittany Nelson. "Molecular Wires Self-Assembled on a Graphite Surface" Langmuir Vol. 25 Iss. 8 (2009)
Available at: http://works.bepress.com/andreas_riemann/6/