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Selected Works of Andreas H. Franz
Presentation
Variable diastereoselectivity in acylation of 2-substituted cyclohexanols
241st American Chemical Society (ACS) National Meeting & Exposition
  • Andrey V. Samoshin, University of the Pacific
  • Jasper Visser
  • Matthew Curtis, University of the Pacific
  • Andreas H. Franz, University of the Pacific
Document Type
Conference Presentation
Department
Chemistry
Organization
American Chemical Society (ACS)
Location
Anaheim, CA
Conference Dates
March 27-31, 2011
Date of Presentation
3-30-2011
Disciplines
Abstract

The ratio of diastereomeric products A and B in acylation of 2-substituted cyclohexanols was found to depend dramatically on the nature of substituents, solvent and additives. Unusual inversion of diastereoselectivity upon change of a solvent or addition of tertiary amines was found for certain combinations of reactants and conditions.

Comments
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Citation Information
Andrey V. Samoshin, Jasper Visser, Matthew Curtis and Andreas H. Franz. "Variable diastereoselectivity in acylation of 2-substituted cyclohexanols" 241st American Chemical Society (ACS) National Meeting & Exposition (2011)
Available at: http://works.bepress.com/andreas-franz/88/