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Article
Tris(1,9-diethyladeninium) triiodide diiodide
Acta Crystallographica, Section C: Crystal Structure Communications
  • Elizabeth F. Day
  • Norman S. Dean
  • Andreas H. Franz, University of the Pacific
Document Type
Article
Department
Chemistry
DOI
10.1107/S0108270106029532
Publication Date
9-1-2006
Disciplines
Abstract
X-ray analysis of the title compound reveals three crystallographically distinct cations of 1,9-diethyl­adeninium, two iodide anions and one triiodide anion in the asymmetric unit, giving six residues and the formula 3C9H14N5+·I3-·2I-. Standard purine nomenclature is used to identify the atoms of each adenine moiety. Hydrogen bonding is observed between atoms N6 and N7 of a pair of cations [N...N = 2.885 (4)/2.902 (3) and 2.854 (3)/2.854 (3) Å], with additional hydrogen bonding to I- anions via the other N6 H atom [N...I = 3.708 (3), 3.738 (3) and 3.638 (3) Å]. The triiodide anion is not involved in hydrogen bonding. The bond lengths and angles of the 1,9-diethyl­adeninium cations are compared with literature values and confirm the formation of the imine tautomer.
Citation Information
Elizabeth F. Day, Norman S. Dean and Andreas H. Franz. "Tris(1,9-diethyladeninium) triiodide diiodide" Acta Crystallographica, Section C: Crystal Structure Communications Vol. C62 Iss. 9 (2006) p. o571 - o573 ISSN: 0108-2701
Available at: http://works.bepress.com/andreas-franz/85/