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Article
Contact of Oil with Solid Surfaces in Aqueous Media Probed Using Sum Frequency Generation Spectroscopy
Langmuir
  • Ping Yuan Hsu, The University Of Akron
  • Ali Dhinojwala, The University Of Akron
Document Type
Article
Publication Date
12-28-2011
Abstract
We have studied the interface between hexadecane droplets and sapphire substrates in water using infrared-visible sum frequency generation spectroscopy (SFG). At high pH and above the isoelectric point of the sapphire substrate, the hexadecane drop is repelled due to electrostatic forces. The SFG measurements are consistent with the observation that a thick layer of water is present between the oil and the sapphire substrate. Below the isoelectric point of the sapphire substrate, the hexadecane drops stick to the sapphire surface. Surprisingly, the SFG results show the presence of a thin layer of water between hexadecane drop and the sapphire substrate. At this contact interface, we observe contributions to the SFG signal from both the hexadecane/water and water/sapphire interfaces. The reasons for the presence of a thin water layer with adhesive contact can be explained due to weaker repulsive double layer and the attractive van der Waals interactions.
Citation Information
Ping Yuan Hsu and Ali Dhinojwala. "Contact of Oil with Solid Surfaces in Aqueous Media Probed Using Sum Frequency Generation Spectroscopy" Langmuir Vol. 28 Iss. 5 (2011) p. 2567 - 2573
Available at: http://works.bepress.com/ali_dhinojwala/88/