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Article
Cavitation and Fracture Behavior of Polyacrylamide Hydrogels
Soft Matter (2009)
  • Santanu Kundu
  • Alfred Crosby, University of Massachusetts - Amherst
Abstract

The mechanical properties of gels present qualitatively contradictory behavior; they are commonly soft but also notoriously brittle. We investigate the elasticity and fracture behavior of swollen polymer networks using a simple experimental method to induce cavitation within a gel and adapt scaling theories to capture the observed transition from reversible to irreversible deformations as a function of polymer volume fraction. It is shown quantitatively that the transition from reversible cavitation to irreversible fracture depends on the polymer volume fraction and an initial defect length scale. The use of cavitation experiments permits characterization of network properties across length scales ranging from µm to mm. We anticipate that these results may significantly enhance the understanding of mechanical properties of soft materials, both synthetic and biological.

Disciplines
Publication Date
July 21, 2009
Publisher Statement
DOI: 10.1039/B909237D
Citation Information
Santanu Kundu and Alfred Crosby. "Cavitation and Fracture Behavior of Polyacrylamide Hydrogels" Soft Matter Vol. 2 Iss. 20 (2009)
Available at: http://works.bepress.com/alfred_crosby/15/