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Article
Quantum Dots by Ultraviolet and X-ray Lithography
Nanotechnology
  • Lane A. Martin
  • Lauren Elizabeth Rich
  • Alexey Yamilov, Missouri University of Science and Technology
  • Brian R. Heckman
  • Nicholas Leventis, Missouri University of Science and Technology
  • Suchi Guha
  • John Katsoudas
  • Ralu Divan
  • Derrick C. Mancini
  • Massimo F. Bertino, Missouri University of Science and Technology
  • Raghuveer Reddy Gadipalli
Abstract
Highly luminescent semiconductor quantum dots have been synthesized in porous materials with ultraviolet and x-ray lithography. For this, the pore-filling solvent of silica hydrogels is exchanged with an aqueous solution of a group II metal ion together with a chalcogenide precursor such as 2-mercaptoethanol, thioacetamide or selenourea. The chalcogenide precursor is photodissociated in the exposed regions, yielding metal chalcogenide nanoparticles. Patterns are obtained by using masks appropriate to the type of radiation employed. The mean size of the quantum dots is controlled by adding capping agents such as citrate or thioglycerol to the precursor solution, and the quantum yield of the composites can be increased to up to about 30% by photoactivation. Our technique is water-based, uses readily available reagents, and highly luminescent patterned composites are obtained in a few simple processing steps. Polydispersity, however, is high (around 50%), preventing large-scale usage of the technique for the time being. Future developments that aim at a reduction of the polydispersity are presented.
Department(s)
Chemistry
Second Department
Physics
Library of Congress Subject Headings
Lithography
Porous materials
Quantum dots
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2007 Institute of Physics - IOP Publishing, All rights reserved.
Publication Date
1-1-2007
Disciplines
Citation Information
Lane A. Martin, Lauren Elizabeth Rich, Alexey Yamilov, Brian R. Heckman, et al.. "Quantum Dots by Ultraviolet and X-ray Lithography" Nanotechnology (2007)
Available at: http://works.bepress.com/alexey-yamilov/18/