Thermophysical Properties in Medium Temperature Range of Several Thio and DithiocarbamatesJournal of Thermal Analysis and Calorimetry (2008)
The present study reports a DSC study of the thio- and dithiocarbamates: 3H-benzoxazole-2-thione (2-mercaptobenzoxazole), 3H-benzothiazole-2-thione (2-mercaptobenzothiazole), thiazolidine-2-thione (2-mercapto-2-thiazoline), oxazolidine-2-thione (2-mercapto2-oxazoline) and tetrahydro-1,3-oxazine-2-thione (5,6-dihydro-4H-1,3-oxazine-2-thiol) in the temperature interval T=268 K and the melting temperatures. Temperatures, enthalpies and entropies of fusion are reported. No solid–solid phase transitions were observed for the compounds in the temperature interval studied. The heat capacity of the compounds as a function of temperature was measured.
- fusion enthalpy,
- heat capacity,
Publication DateFebruary 1, 2008
Citation InformationManuel Temprado, Maria Victoria Roux, Archana R. Parameswar, Alexei V. Demchenko, et al.. "Thermophysical Properties in Medium Temperature Range of Several Thio and Dithiocarbamates" Journal of Thermal Analysis and Calorimetry Vol. 91 Iss. 2 (2008) p. 471 - 475
Available at: http://works.bepress.com/alexei-demchenko/95/