2-Allylphenyl Glycosides as Complementary Building Blocks for Oligosaccharide and Glycoconjugate SynthesisBeilstein Journal of Organic Chemistry (2012)
The O-allylphenyl (AP) anomeric moiety was investigated as a new leaving group that can be activated for chemical glycosylation under a variety of conditions, through both direct and remote pathways. Differentiation between the two activation pathways was achieved in a mechanistic study. The orthogonal-type activation of the AP moiety along with common thioglycosides allows for the execution of efficient oligosaccharide assembly.
Publication DateApril 18, 2012
Citation InformationHemali D Premathilake and Alexei V Demchenko. "2-Allylphenyl Glycosides as Complementary Building Blocks for Oligosaccharide and Glycoconjugate Synthesis" Beilstein Journal of Organic Chemistry Vol. 8 Iss. 1 (2012) p. 597 - 605
Available at: http://works.bepress.com/alexei-demchenko/54/