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Article
Transition‐Metal‐Mediated Glycosylation with Thioglycosides
Chemistry - A European Journal (2022)
  • Samira Escopy, University of Missouri–St. Louis
  • Alexei Demchenko, University of Missouri-St. Louis
Abstract
Thioglycosides are among the most common glycosyl donors that find broad application in the synthesis of glycans and glycoconjugates. However, the requirement for toxic and/or large access of activators needed for common glycosylations with thioglycosides remains a notable drawback. Due to the increased awareness of the chemical waste impact on the environment, synthetic studies have been driven by the goal of finding non-toxic reagents. The main focus of this review is to highlight recent methods for thioglycoside activation that rely on transition metal catalysis.
Publication Date
March 7, 2022
DOI
10.1002/chem.202103747
Citation Information
Samira Escopy and Alexei Demchenko. "Transition‐Metal‐Mediated Glycosylation with Thioglycosides" Chemistry - A European Journal Vol. 28 Iss. 14 (2022)
Available at: http://works.bepress.com/alexei-demchenko/179/