Article
Rare Earth Arylsilazido Compounds with Inequivalent Secondary Interactions
Ames Laboratory Accepted Manuscripts
Publication Date
1-1-2018
Department
Ames Laboratory; Chemistry
Report Number
IS-J 9677
DOI
10.1039/C8CC03186J
Journal Title
Chemical Communications
Abstract
A new bulky silazido ligand, –N(SiHMe2)Dipp (Dipp = C6H3-2,6-iPr2) supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe2)Dipp}3 (Ln = Sc, Y, Lu) that each contain three secondary Ln↼HSi interactions and one agostic CH bond. Y{N(SiHMe2)Dipp}3 and acetophenone react via hydrosilylation, rather than by insertion into the Y–N bond or enolate formation.
Language
en
Publisher
Iowa State University Digital Repository, Ames IA (United States)
Disciplines
Citation Information
Kasuni C. Boteju, Suchen Wan, Amrit Venkatesh, Arkady Ellern, et al.. "Rare Earth Arylsilazido Compounds with Inequivalent Secondary Interactions" (2018) Available at: http://works.bepress.com/aaron_sadow/56/