Article
Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand
Chemical Communications
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
1-1-2017
DOI
10.1039/C6CC09304C
Abstract
A β-SiH functionalized benzyl anion [C(SiHMe2)2Ph]− is obtained by deprotonation of HC(SiHMe2)2Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)3CPh; LnI3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe2)2Ph}3 (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.
Creative Commons License
Creative Commons Attribution 3.0
Copyright Owner
Royal Society of Chemistry
Copyright Date
2017
Language
en
File Format
application/pdf
Citation Information
Aaron D. Sadow, Kasuni C Boteju and Arkady Ellern. "Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand" Chemical Communications Vol. 53 Iss. 4 (2017) p. 716 - 719 Available at: http://works.bepress.com/aaron_sadow/47/
This article is published as Boteju, Kasuni C., Arkady Ellern, and Aaron D. Sadow. "Homoleptic organolanthanide compounds supported by the bis (dimethylsilyl) benzyl ligand." Chemical Communications 53, no. 4 (2017): 716-719. 10.1039/C6CC09304C